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11.
New pyrrolylalkanethiolate-stabilized gold and palladium nanoparticles have been prepared: electrochemical polymerization of their metal nanoparticles and their TEMPO-derivatized metal nanoparticles gave the remarkably stable poly(pyrrole metal nanoparticle) films on metal electrodes. 相似文献
12.
The efficient and novel bifunctional organocatalyst for the enantioselective aza-Morita-Baylis-Hillman (aza-MBH) reaction has been established with (S)-3-(N-isopropyl-N-3-pyridinylaminomethyl)BINOL for the first time. The reaction proved to be deeply influenced by the position of the Lewis base attached to BINOL. The acid-base-mediated functionalities for the activation of the substrate and the fixing of conformation of the organocatalyst are harmoniously performed to promote the reaction with high enantiocontrol. 相似文献
13.
Osako T Terada S Tosha T Nagatomo S Furutachi H Fujinami S Kitagawa T Suzuki M Itoh S 《Dalton transactions (Cambridge, England : 2003)》2005,(21):3514-3521
The structure and dioxygen-reactivity of copper(I) complexes R supported by N,N-bis(6-methylpyridin-2-ylmethyl)amine tridentate ligands L2R[R (N-alkyl substituent)=-CH2Ph (Bn), -CH2CH2Ph (Phe) and -CH2CHPh2(PhePh)] have been examined and compared with those of copper(I) complex (Phe) of N,N-bis[2-(pyridin-2-yl)ethyl]amine tridentate ligand L1(Phe) and copper(I) complex (Phe) of N,N-bis(pyridin-2-ylmethyl)amine tridentate ligand L3(Phe). Copper(I) complexes (Phe) and (PhePh) exhibited a distorted trigonal pyramidal structure involving a d-pi interaction with an eta1-binding mode between the metal ion and one of the ortho-carbon atoms of the phenyl group of the N-alkyl substituent [-CH2CH2Ph (Phe) and -CH2CHPh2(PhePh)]. The strength of the d-pi interaction in (Phe) and (PhePh) was weaker than that of the d-pi interaction with an eta2-binding mode in (Phe) but stronger than that of the eta1 d-pi interaction in (Phe). Existence of a weak d-pi interaction in (Bn) in solution was also explored, but its binding mode was not clear. Redox potentials of the copper(I) complexes (E1/2) were also affected by the supporting ligand; the order of E1/2 was Phe>R>Phe. Thus, the order of electron-donor ability of the ligand is L1Phe相似文献
14.
Fumio Yoneda Ryosuke Koga Sadao Nishigaki Shinobu Fukazawa 《Journal of heterocyclic chemistry》1982,19(4):949-951
Treatment of 6-amino-1,3-dimethyl-5-nitrosouracil (Ia) with dimethyl acetylenedicarboxylate (DMAD) in dimethylformamide (DMF) afforded 6,7-bis(dimethoxycarbonyl)-1,3-dimethyllumazine (II). Similarly, the reaction of 6-amino-1,3-dimethyl-5-phenylazouracil with DMAD gave also II. Hydrolysis of II with hydrochloric acid gave 1,3-dimethyllumazine-6-carboxylic acid (III). III was chlorinated with thionyl chloride and then aminated with ethanolic ammonia to give rise to 6-carbamoyl-1,3-dimethyllumazine (V). V was alternatively synthesized by the treatment of Ia with propiolamide in DMF. 相似文献
15.
16.
When milled together with bismuth shot in the presence of allyl halide, aromatic aldehydes readily underwent a Barbier-type allylation to afford the corresponding homoallyl alcohols in good yield. In contrast to the failure in solution reaction, aromatic ketones also underwent allylic carbonyl addition under solvent-free conditions to give the expected tertiary homoallyl alcohols in moderate to good yield. 相似文献
17.
Fabrication of mesoporous ZnO nanosheets from precursor templates grown in aqueous solutions 总被引:1,自引:0,他引:1
Keita Kakiuchi Eiji Hosono Toshio Kimura Hiroaki Imai Shinobu Fujihara 《Journal of Sol-Gel Science and Technology》2006,39(1):63-72
Mesoporous ZnO nanosheets were successfully prepared by pyrolytic transformation of zinc carbonate hydroxide hydrate, Zn4CO3(OH)6·H2O. The nanosheets were initially formed as assemblies on glass substrates during chemical bath deposition (CBD) in aqueous
solutions of urea and zinc acetate dihydrate, zinc chloride, zinc nitrate hexahydrate, or zinc sulfate heptahydrate at 80°C.
It was key to induce heterogeneous nucleation of Zn4CO3(OH)6·H2O by promoting a gradual hydrolysis reaction of urea and controlling the degree of supersaturation of zinc hydroxide species.
Morphology of Zn4CO3(OH)6·H2O was largely influenced by the anions present in the CBD solutions. The Zn4CO3(OH)6·H2O nanosheets were transformed into wurtzite ZnO by heating at 300°C in air without losing the microstructural feature. 相似文献
18.
Generalization of the release process through the wax matrix layer was examined by use of a reservoir device tablet. The wax matrix layer of the reservoir device tablet was prepared from a physical mixture of lactose and hydrogenated castor oil to simplify the release properties. Release through the wax matrix layer showed zero-order kinetics in a steady state after a given lag time, and could be divided into two stages. The first stage was the formation process of water channel by dissolving the soluble component in the wax matrix layer. The lag time obtained by applying the square root law equation was well connected with the amount of the matrix layer and mixed weight ratio of components in this layer. The second stage was the zero-order release process of drug in the reservoir through the wax matrix layer, because the effective surface area was fixed. The release rate constants were connected with thickness of the matrix layer and permeability coefficient, and the permeability coefficients were connected with the diffusion coefficient of drug and porosity. Hence the release rate constant could be connected with the amount of matrix layer and the mixed weight ratio of components in the matrix layer. It was therefore suggested that the release process could be generalized using the amount of matrix layer and the mixed weight ratio of components in the matrix layer. 相似文献
19.
[reaction: see text] This paper describes a novel method to synthesize a quinoline backbone by incorporating allenyl cations into a catalytic intramolecular Friedel-Crafts reaction. The initial products were isomerized and aromatized upon treatment with acid and base, respectively, to give quinolines. The basic concept also proved to be promising for 1-benzazepine, 1-benzazocine, or isoquinoline synthesis. 相似文献
20.
High concentrations of arsenic were observed in the blubber of ringed seals (Pusa hispida) in our previous study. To better understand the arsenic accumulation in blubber of marine mammals, arsenicals in the blubber of ringed seal were characterized using high performance liquid chromatography–inductively coupled plasma mass spectrometry (HPLC–ICPMS). The most predominant water-soluble arsenical in the blubber was dimethylarsinic acid (DMA), in spite of the predominance of arsenobetaine in other tissues. Lipid-soluble fraction was hydrolyzed under mild (tetraethylammonium hydroxide (TEAH) hydrolysis) and strong (NaOH hydrolysis) conditions, and then an aliquot of hydrolysate was injected onto HPLC–ICPMS. Both TEAH-labile and TEAH-stable/NaOH-labile lipid-soluble fractions contained precursors of DMA. These results suggest that the blubber might be the pool of DMA and DMA-containing precursors in ringed seals. 相似文献